Product ID:140-0506 GLOSS BLACK, SUPER ACRYLIC (SUPDAT)
MSDS Date:07/01/1993
FSC:8010
NIIN:00N045006
MSDS Number: BSDKR

SHERWIN-WILLIAMS CO

101 PROSPECT AVE
CLEVELAND, OH 44115
US

Emergency Phone: 216-566-2917

Info Phone: 216-566-2902

Cage: 54636

SHERWIN-WILLIAMS CO THE

CLEVELAND, OH 44115-1042 US

Telephone: 800-251-2486/216-566-2242

Cage: 54636

VOLATILE ORGANIC CONTENT AS A PERCENT BY WEIGHT, PER BAAQMD

RTECS: 9999999VO

OSHA PEL N/K

ACGIH TLV: N/K

AT 250 MG/M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH

RTECS: 9999999ZZ

ETHYL KETONE MAY INCREASE NERV SYS EFTS OF OTHER

RTECS: 9999999ZZ

SOLVENTS W/PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE.

RTECS: 9999999ZZ

DEPRESSURIZE CNTNR. DISPOSE OF I/A/W

RTECS: 9999999ZZ

NUISANCE DUSTS ARE ACGIH TLV 10 MG/M3 (TOTAL

RTECS: 9999999ZZ

(RESPIRABLE FRACTION). VAPS WILL ACCUM READILY & MAY

RTECS: 9999999ZZ

KEEP AREA VENTILATED. DO NOT SMOKE. EXTING

RTECS: 9999999ZZ

ELEC TOOLS & APPLIANCES, & ANY OTHER SOURCES OF

RTECS: 9999999ZZ

PROC. CONTENTS UNDER PRESS. DO NOT PUNCTURE,

RTECS: 9999999ZZ

RADIATORS, STOVES, HOT WATER, & OTHER HEAT SOURCES

RTECS: 9999999ZZ

KEEP OUT OF REACH OF CHILDREN. INTENTIONAL MISUSE BY

RTECS: 9999999ZZ

RESP APPRVD BY NIOSH/MSHA FOR PROT AGAINST

RTECS: 9999999ZZ

REFER TO OSHA STDS 1910.94, 1910.107, 1910.108.

RTECS: 9999999ZZ

760

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: 14%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT

760

CAS: 75-28-5

RTECS: TZ4300000

Fraction By Weight: 14%

OSHA PEL N/K

ACGIH TLV: N/K

22

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 17%

OSHA PEL 200 PPM; Z-2

ACGIH TLV: S, 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

7.1

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 2%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/125 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

5.9

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 14%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/150 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

SOLVENT NAPHTHA (PETROLEUM), LIGHT AROMATIC; (NAPHTHA,

CAS: 64742-95-6

RTECS: WF3400000

Fraction By Weight: 3%

OSHA PEL N/K

ACGIH TLV: N/K

180

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 22%

OSHA PEL 1000 PPM

ACGIH TLV: 750 PPM/1000 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

Fraction By Weight: 2%

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TOLUENE APPEARS ON THE NAVY LISTING OF
OCCUP CHEM REPROD HAZARDS. SEEK CONSULTATION FROM APPROP HLTH
PROFESSIONALS CONCERNING LATEST HAZARD LIST INFO & SAFE HNDLG &
EXPOS INFO . ACUTE:IRRIT OF E YES, SKIN & RESP SYS. MAY CAUSE NERV
SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON, & POSSIBLY DEATH.
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:SIGNS & SYMPS OF OVEREXP:HDCH, DIZZ,
NAUS, & LOSS OF COORDINATION ARE INDICATIONS OF EXCESS EXPOS TO
VAPS/SPRAY MISTS. REDNESS & ITCHING/BURNING SENSATION MAY INDICATE
EYE/EXCESS SKIN EXPOS. CHRONIC:PRLNGD OVEREXP TO SOLV INGREDS MAY
CAUSE ADVERSE EFTS TO LIVER, URINARY, CARDIOVASCULAR, & REPROD
(SUPDAT)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:INHAL:REMOVE FROM EXPOS. RESTORE BRTHG. KEEP WARM & QUIET.
SKIN:WASH AFFECTED AREA THORO W/SOAP & WATER. REMOVE CONTAMD CLTHG
& LAUNDER BEFORE RE-USE. EYES:FLUSH W/LG AMTS OF WATER FOR @ LEAST
15 MINS . GET MED ATTN. INGEST:SEEK MEDICAL ATTENTION.

Flash Point Method:PMCC
Flash Point:<0F,<-18C
Lower Limits:0.7%
Upper Limits:12.8%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZ ARE PREF.
WATER MAY BE USED TO COOL CLSD CNTNRS(SUPDAT)
Unusual Fire/Explosion Hazard:ISOLATE FROM HEAT, ELEC QUIP, SPKS, &
OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME HEAT.
APPLIC TO HOT SURF REQS SPEC PREC. DURING EMER (SUPDAT)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:USE ONLY W/ADEQ VENT. AVOID BRTHG VAP
& SPRAY MIST. AVOID CONT W/SKIN & EYES. CONTENTS ARE EXTREMELY
FLAMM. KEEP AWAY FROM HEAT, SPKS, & OPEN FLAME.
Other Precautions:THESE COATINGS MAY CNTN MATLS CLASSIFIED AS NUISANCE
PARTICULATED (LISTED "AS DUST" IN INGREDS) WHICH MAY BE PRESENT @
HAZ LEVS ONLY DURING SANDING/ABRADING OF DRIED FILM. IF NO SPECIFIC
DUSTS ARE LIS TED IN INGREDS, APPLIC LIMS FOR (ING 14)

Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLIC LIMS BY VENT, WEAR NIOSH/MSHA APPRVD PROPERLY FITTED ORG
VAP/PARTICULATE RESP FOR PROT AGAINST MATLS IN INGREDS. WHEN
SANDING/ABRADING DRIED FILM, W EAR NIOSH/MSHA APPRVD DUST/MIST (ING
21)
Ventilation:LOC EXHAUST PREF. GEN EXHAUST ACCEPTABLE IF EXPOS TO MATLS
IN INGREDS IS MAINTAINED BELOW APPLIC EXPOS LIM. (ING 22)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGG .
Other Protective Equipment:ANSI APPRVD EMERGENCY EYE WASH & DELUGE
SHOWER .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
MFR TRADE NAME/PART NO:CONTROLS RUST SPRAY ENAMEL. FIRE FIGHT PROC:TO
PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOS TO EXTREME
HEAT. EXPLO HAZ:CNDTNS OVEREXP TO DECOMP PROD MAY CAUSE HLTH HAZ.
SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN. EFTS OF
OVEREXP:SYS. RATS EXPOS TO TITANIUM DIOXIDE DUST (ING 10)

Boiling Pt:B.P. Text:<360F,<182C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE:CARBON DIOXIDE, CARBON
MONOXIDE.

Waste Disposal Methods:WASTE FROM THIS PROD MAY BE HAZ AS DEFINED UNDER
RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERM
APPLIC EPA HAZ WASTE NUMBERS. WASTE FROM PROD CNTNG METHYL ETHYL
KETONE MAY ALSO REQ T ESTING FOR EXTRACTABILITY. DO NOT INCIN. (ING
13)

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particular situation.